Azobenzene-Derivative From the Coupling Reaction of Primary Amine Through Dicobalt Cataltic Reaction
碩士 === 國立中興大學 === 化學系 === 90 === Reaction of Co2(CO)8 with HC≡CC6H4NH2 in THF at 55°C for 3 hours affords an unusual complex {[Co2(CO)6(μ-HC≡C-)]-C6H4N=}2 1 in reasonable yield. The crystal structure of 1 reveals that it can be regarded as two alkyne-bridged dicobalt fragments being unite...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2002
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| Online Access: | http://ndltd.ncl.edu.tw/handle/38296579224688973964 |