Synthesis and Reactions of Se-substituted Complexes of Tungsten (Ⅱ) and Molybdenum (Ⅱ)

碩士 === 國立臺灣大學 === 化學研究所 === 87 === Treatment of [Cp(CO)3M(NCCH3)]+BF4- (M = W, Mo) with potassium selenocyanate afforded selenium-bonded complexes Cp(CO)3M(SeCN) (M = W(1a), Mo(1b)) through nucleophilic substitution. Further reactions of 1a and 1b with various phosphine reagents afforded...

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Bibliographic Details
Main Authors: Li, Yu-Shiou, 黎渝秀
Other Authors: Ph. D. Lin, Ying-Chih
Format: Others
Language:en_US
Published: 1999
Online Access:http://ndltd.ncl.edu.tw/handle/51784634917009489191