Samarium ( III ) Chloride - Chiral Phosphorus ( V ) complexes as the Catalyst in Asymmetric Addition of Trimethylsilyl Cyanide to Aldehydes

博士 === 國立臺灣大學 === 化學系 === 86 === chiral-phosphoramidate reagents 3a-c were prepared from ephedrines and POCl3, followed by treatment with ethylenediamine. Using very small amounts of SmCl3 (0.1 mol%) and the C2-symmetric chiral ligand 3a (o...

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Bibliographic Details
Main Authors: Yang, Wen-Bin, 楊文彬
Other Authors: Jim-Min Fang
Format: Others
Language:zh-TW
Published: 1998
Online Access:http://ndltd.ncl.edu.tw/handle/50420679485756810903