The Study of Nickel Complexes Catalyze the Conbon-Conbon Bond reaking and Formation of Nitriles
碩士 === 國立清華大學 === 化學學系 === 82 === 1-bromo-2-methylnaphthalene在NiCl2(PPh3)2-Zn的催化系統中,以 CH3 CN作為溶劑,並不會今進行自偶合反應,而是鎳錯合物將CH3CN的碳-碳鍵打 斷,這個斷裂後生成的CN-陰離子,再取代1-bromo-2-methylnaphthal ene 上的溴原子,生成2-methyl-1-naphthonitrile,目前為止,催化反應的產率 最...
| Main Authors: | , |
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| Format: | Others |
| Language: | zh-TW |
| Published: |
1994
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| Online Access: | http://ndltd.ncl.edu.tw/handle/56353593421205963931 |