Synthesis and Reactivity of Allylic Amines in Palladium Catalysis

Reaction of unsymmetrical allylic electrophiles with amines gives rise to regioisomeric allylamines. It was found that linear products result from the thermodynamically controlled isomerization of the corresponding branched products, which form initially. The isomerization was found to be promoted b...

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Bibliographic Details
Main Author: Dubovyk, Igor
Other Authors: Yudin, Andrei
Language:en_ca
Published: 2012
Subjects:
Online Access:http://hdl.handle.net/1807/33984