Applications of α-Keto Carbocations in Carbon-Carbon and Carbon-Nitrogen Bond Formation
This thesis describes synthetic applications of α-keto carbocations, which represent potentially useful, but poorly studied, reversed polarity equivalents of enolates. In the first chapter, a Ag(I) – mediated method for the nucleophilic displacement of α-halocarbonyl compounds to construct carbon-ca...
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| Language: | en_ca |
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2011
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| Online Access: | http://hdl.handle.net/1807/32798 |