Synthesis of the naturally occurring cyclopropenoids malvalic and sterculic acids
The two naturally occurring cyclopropene fatty acids, sterculic and malvalic, have been synthesized. The cyclopropene ring was made by inserting a methylene unit into an acetylenic linkage. The synthesis of methyl sterculate was repeated using diethyl aluminum chloride, diazomethane, and methyl stea...
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| Language: | en_US |
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2012
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| Online Access: | http://hdl.handle.net/1957/26781 |