Multi-edge X-ray absorption spectroscopy and electronic structure calculations of biomimetic model complexes of the H-cluster of [FeFe]-hydrogenase
FeFe-hydrogenases are members of a family of metalloenzymes that catalyze the conversion of protons and electrons to dihydrogen at a remarkable rate. The catalytic center of this enzyme, the H-cluster, contains a classical [4Fe-4S] cluster that is covalently and magnetically coupled through a cystei...
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| Language: | en |
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2012
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| Online Access: | http://etd.lib.montana.edu/etd/2012/giles/GilesL0512.pdf |