Development of New Carbon-Carbon Bond-Forming Strategies: Formation and Reactivity of sp³-gem-Organodimetallic Palladium(II)/MRn Alkane Intermediates (MRn=Dialkylalumino, Trialkylstannyl)

Development of New Carbon-Carbon Bond-Forming Strategies: Formation and Reactivity of sp³-gem-Organodimetallic Palladium(II)/MRn Alkane Intermediates (MRn=Dialkylalumino, Trialkylstannyl)

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Investigation of the catalytic formation, reactivity and synthetic scope of sp³-gem-organodimetallic palladio(II)/main group metal (main group metal = tributylstannyl, dialkylalumino) alkane species has been carried out. Insight was expanded regarding the inter- and intramolecular reactivity of viny...

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Bibliographic Details
Main Author: Trepanier, Vincent Hector Emile
Format: Others
Language:en
Published: 2006
Subjects:
palladium
aluminum
tin
stannane
alane
methodology
mechanistic studies
stereospecific
ligand migration
all-carbon quaternary benzylic stereocentre
carbon-carbon bond formation
carbopalladation
cyclopropanation
allylation
dimerisation
C-H insertion
deuterium labeling
Chemistry
Online Access:http://hdl.handle.net/10012/2608

Internet

http://hdl.handle.net/10012/2608

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