Investigating Rings: From Iridium-Catalyzed [4+2] Cycloadditions of Alkynyl Halides to Ring Openings of Cyclopropanated Oxabenzonorbornadiene

This thesis describes two unrelated projects. Iridium-catalyzed intramolecular [4+2] cycloadditions of alkynyl halides were investigated, and the catalyst conditions were optimized for ligand, solvent, and temperature. Several substrates successfully underwent cycloaddition under the optimized condi...

Full description

Bibliographic Details
Main Author: Tigchelaar, Andrew
Language:en
Published: 2012
Online Access:http://hdl.handle.net/10214/3930