Total synthesis of (+-) neoverrucosan-5B-ol, (+-)-homoverrucosan-5B-ol, (+-)-verrucosan-2B-ol, and (+-)-(3R,4R,5R,6S,9R)-cyatha-12,18-diene : a new cyclohexenone annulation sequence

The total syntheses of four structurally related, naturally occurring compounds, (±)­verrucosan-2β-ol (61), (±)-neoverrucosan-5β-ol (62), (±)-homoverrucosan-5β,-ol (63), and (±)-(3R, 4R, 5R, 6S, 9#)-cyatha-12,18-diene (64) are discussed in the first part of this thesis. In connection with the total...

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Bibliographic Details
Main Author: Boulet, Serge L.
Language:English
Published: 2009
Online Access:http://hdl.handle.net/2429/9454