Asymmetric induction and triplet sensitization in the solid state photochemistry of Anti-9-carboxybenzonorbornadiene
[Formula] Acid 19 and its methyl ester 45 were prepared, and studies of their photochemical reactivity were made in both the solution phase and solid state. Unexpectedly, both compounds underwent di-7r.-meth.ane rearrangement to the corresponding undecatrienes 54 and 53 upon direct irradiation i...
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| Language: | English |
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2009
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| Online Access: | http://hdl.handle.net/2429/8159 |