Hydride, alkyl, and alkenyl complexes of tungsten
Hydrogenation of Cp*W(NO)(CH₂SiMe₃)₂ affords the 16-electron alkyl hydride complex, Cp*W(NO)(CH₂SiMe₃)H, as a reactive intermediate. The tungsten-hydride bond of this complex inserts unsaturated reagents such as nitriles, ketones and aldehydes, imines, and acetylenes to form stable products conta...
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| Language: | English |
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2009
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| Online Access: | http://hdl.handle.net/2429/7061 |