Cationic carbonyl derivatives of electron-rich metals-syntheses, structures, and spectroscopic properties
The range of thermally stable, predominantly a-bonded metal carbonyl derivatives has been expanded to include Pd(I), Pd(II), Ir(III), Os(II), and Ru(II). The new compounds, [Pd(CO)₄][Sb₂F₁₁]₂, cis-Pd(CO)₂(SO₃F)₂, [Pd₂(µ-CO)₂](SO₃F)₂, [Pd₂(µ -CO) ₂][Sb₂₁₁]₂, mer- Ir(CO)₃(SO₃F)₃, [Ir(CO)₅Cl][Sb₂ F₁...
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| Language: | English |
| Published: |
2009
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| Online Access: | http://hdl.handle.net/2429/6178 |