Heterocumulene insertions with group 6 Diaryl Nitrosyl complexes
Treatment of the 16-electron complexes Cp*M(NO)(aryl)2 (Cp* = i5-05Me5; M =Mo, W; aryl = phenyl, o-tolyl, p-tolyl) with the heterocumulenes carbon dioxide, p-tolylisocyanate, and carbon disulfide leads to the i2-carboxylate-, i2-amide-, and i2-thiocarboxylate-containing complexes, respectively, in 1...
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| Language: | English |
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2008
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| Online Access: | http://hdl.handle.net/2429/2203 |