Substituted aryl glycosides as probes of the mechanism of spontaneous ad enzyme-catalyzed glycoside hydrolysis

A series of mono-substituted deoxy and deoxyfluoro 2',4'-dinitrophenyl P-D-glycopyranosides (DNP glycosides) was synthesized and used to probe the mechanisms of spontaneous and enzyme-catalyzed hydrolysis of 0-glycosides. The relative rates of spontaneous hydrolysis of the DNP glucosides f...

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Bibliographic Details
Main Author: Namchuck, Mark N.
Language:English
Published: 2008
Online Access:http://hdl.handle.net/2429/1910