Development of tungsten nitrosyl alkylidene complexes for activation of hydrocarbons
series of tungsten alkyls of stoichiometry Cp'W(NO)(R)(R') [Cp' = Cp, Cp*; R = CH₂CMe₃ , CHȈ2CMe₂Ph, CH₂SiMe₃ ; R' = CH₂CMe₃ , CH₂CMe₂Et, CH₂CMe₂Ph, CH₂SiMe₃, CH₃, Ph, C l , CH₂Ph, OCH₃, NME₂ ] is shown by NMR and, in some cases, IR spectroscopies to adopt an a-agostic structu...
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| Language: | English |
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2009
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| Online Access: | http://hdl.handle.net/2429/13226 |