Method Development for the Stereoselective Synthesis of Medium-Sized Cyclic Ethers and Application to Natural Product Synthesis: Part I. Organocatalytic Oxa-Conjugate Addition for α,α´-trans-Oxepanes Part II. Gold(I)-Catalyzed Alkoxylation for α,α´-cis-Oxocenes Part III. Studies toward the Synthesis

Method Development for the Stereoselective Synthesis of Medium-Sized Cyclic Ethers and Application to Natural Product Synthesis: Part I. Organocatalytic Oxa-Conjugate Addition for α,α´-trans-Oxepanes Part II. Gold(I)-Catalyzed Alkoxylation for α,α´-cis-Oxocenes Part III. Studies toward the Synthesis

<p>Medium-sized cyclic ethers are challenging synthetic targets due to enthalpic and entropic barriers. Methods for the stereoselective synthesis of &#945;,&#945;&#900;-disubstituted medium-sized cyclic ethers began to appear with the discovery of naturally-occurring, ladder-shaped...

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Bibliographic Details
Main Author: Lanier, Megan
Other Authors: Hong, Jiyong
Published: 2015
Subjects:
Organic chemistry
cyclic ether
gold(I)-alkoxylation
intricenyne
organocatalyzed oxa-conjugate addition
oxepane
oxocene
Online Access:http://hdl.handle.net/10161/9941

Internet

http://hdl.handle.net/10161/9941

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