Experimental observation and quantum chemical investigation of thallium(I) (Z)-methanediazotate: synthesis of a long sought and highly reactive species

Experimental observation and quantum chemical investigation of thallium(I) (Z)-methanediazotate: synthesis of a long sought and highly reactive species

For the first time, successful synthesis and characterisation of the missing (Z)-isomer of thallium(I) methanediazotate has been accomplished, utilising low-temperature NMR monitoring analysis. The title compound was synthesised from N-methyl-N-nitrosourea and thallium(I) propoxide, under sub-ambien...

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Bibliographic Details
Main Authors: Singh, Neeraj, Fiedler, Benjamin, Friedrich, Joachim, Banert, Klaus
Other Authors: Technische Universität Chemnitz, Fakultät für Naturwissenschaften
Format: Article
Language:English
Published: Universitätsbibliothek Chemnitz 2017
Subjects:
Isomerie
Computerchemie
Magnetische Kernresonanz
Technische Universität Chemnitz
Publikationsfonds
reactive intermediate
nuclear magnetic resonance
computational chemistry
urea
isomerism
Chemnitz University of Technology
Publication funds
ddc:547
Computational chemistry
Harnstoff
Online Access:http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-224226
http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-224226
http://www.qucosa.de/fileadmin/data/qucosa/documents/22422/c7ra00872d.pdf
http://www.qucosa.de/fileadmin/data/qucosa/documents/22422/c7ra00872d1.pdf
http://www.qucosa.de/fileadmin/data/qucosa/documents/22422/signatur.txt.asc

Internet

http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-224226
http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-224226
http://www.qucosa.de/fileadmin/data/qucosa/documents/22422/c7ra00872d.pdf
http://www.qucosa.de/fileadmin/data/qucosa/documents/22422/c7ra00872d1.pdf
http://www.qucosa.de/fileadmin/data/qucosa/documents/22422/signatur.txt.asc

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