Synthetic, Kinetic and Mechanistic Studies in Early Transition Metal Systems. I. α- and β-Hydrogen Elimination Reactions in Derivatives of Permethyltitanocene, -Zirconocene, and -Hafnocene. II. The Reactions of Aluminum Alkyls with Derivatives of Permethylniobocene
<p>The thermal decomposition of Cp*<sub>2</sub>Ti(CH<sub>3</sub>)<sub>2</sub> (Cp* ≡ ƞ<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>) toluene solution follows cleanly first-order kinetics and produces a single titanium product...