Synthetic, Kinetic and Mechanistic Studies in Early Transition Metal Systems. I. α- and β-Hydrogen Elimination Reactions in Derivatives of Permethyltitanocene, -Zirconocene, and -Hafnocene. II. The Reactions of Aluminum Alkyls with Derivatives of Permethylniobocene
<p>The thermal decomposition of Cp*<sub>2</sub>Ti(CH<sub>3</sub>)<sub>2</sub> (Cp* ≡ ƞ<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>) toluene solution follows cleanly first-order kinetics and produces a single titanium product...
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https://thesis.library.caltech.edu/8091/1/McDade%201985.pdfMcDade, Christine (1985) Synthetic, Kinetic and Mechanistic Studies in Early Transition Metal Systems. I. α- and β-Hydrogen Elimination Reactions in Derivatives of Permethyltitanocene, -Zirconocene, and -Hafnocene. II. The Reactions of Aluminum Alkyls with Derivatives of Permethylniobocene. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/B308-3A48. https://resolver.caltech.edu/CaltechTHESIS:02202014-135322611 <https://resolver.caltech.edu/CaltechTHESIS:02202014-135322611>