The synthesis and reactivity of new niobium (V) polyhydrides
The synthesis of new niobium polyhydrides by high pressure hydrogenation of Cp*NbMe_4 in the presence of trapping phosphines is reported. The complexes Cp*NbL_2H_4, L=PMe_3, PMe_2Ph, PMe_2Cy, and L_2=bis(dimethylphosphino)ethane, are described. They exchange D_2 into the hydride positions, and react...
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Format: | Others |
Language: | en |
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1983
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Online Access: | https://thesis.library.caltech.edu/5757/1/Olsen_w_1983.pdf Olson, Wendy A. (1983) The synthesis and reactivity of new niobium (V) polyhydrides. Master's thesis, California Institute of Technology. doi:10.7907/e6p9-e788. https://resolver.caltech.edu/CaltechTHESIS:04292010-145411166 <https://resolver.caltech.edu/CaltechTHESIS:04292010-145411166> |
Internet
https://thesis.library.caltech.edu/5757/1/Olsen_w_1983.pdfOlson, Wendy A. (1983) The synthesis and reactivity of new niobium (V) polyhydrides. Master's thesis, California Institute of Technology. doi:10.7907/e6p9-e788. https://resolver.caltech.edu/CaltechTHESIS:04292010-145411166 <https://resolver.caltech.edu/CaltechTHESIS:04292010-145411166>