Part 1. B-ferrocenylalkyl carbonium ions. Part 2. The stereospecific syntheses of the exo and endo isomers of a-hydroxymethyl-1,2-tetramethyleneferrocene

Part I The solvolysis mechanism of [Beta]-ferrocenylalkyl tosylates is discussed. Evidence is presented which shows that solvolysis occurs with preferential participation of the interannular electrons of the ferrocene moiety leading to intermediate formation of very stable carbonium ions. The produ...

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Bibliographic Details
Main Author: Nugent, Maurice Joseph
Format: Others
Published: 1965
Online Access:https://thesis.library.caltech.edu/185/1/Nugent_mj_1965.pdf
Nugent, Maurice Joseph (1965) Part 1. B-ferrocenylalkyl carbonium ions. Part 2. The stereospecific syntheses of the exo and endo isomers of a-hydroxymethyl-1,2-tetramethyleneferrocene. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/8FWY-7415. https://resolver.caltech.edu/CaltechETD:etd-01152004-112000 <https://resolver.caltech.edu/CaltechETD:etd-01152004-112000>