Stabilization of carbonium ions in the vicinity of metallocene nuclei
A remarkable stabilization imparted to a carbonium ion by an adjacent metallocene nucleus has been demonstrated by a solvolytic study of substituted metallocenylcarbinyl acetates. The solvolysis mechanism has be shown to be to be an uncatalyzed alkl-oxygen fission of the neutral ester by a study of...
Internet
https://thesis.library.caltech.edu/1631/1/Hill_ea_1961.pdfHill, Elgin Alexander (1961) Stabilization of carbonium ions in the vicinity of metallocene nuclei. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/RPVG-GP20. https://resolver.caltech.edu/CaltechETD:etd-05052006-111842 <https://resolver.caltech.edu/CaltechETD:etd-05052006-111842>