The Ester Enolate Claisen Rearrangement. I. Sterochemical Control Through Stereoselective Enolate Formation. II. Construction of the Prostanoid Skeleton

The Ester Enolate Claisen Rearrangement. I. Sterochemical Control Through Stereoselective Enolate Formation. II. Construction of the Prostanoid Skeleton

<p>Part I:</p> <p>The [3,3]-sigmatropic rearrangement of a number of allylic esters 1, as the enolate anions of the corresponding silyl ketene acetals, produces the γ,δ-unsaturated acids 2 in 66 - 88% yield. The mild conditions allow rearrangement of acid sensitive and therma...

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Bibliographic Details
Main Author: Willard, Alvin Keith
Format: Others
Published: 1976
Online Access:https://thesis.library.caltech.edu/10582/1/Willard_AK_1976.pdf
Willard, Alvin Keith (1976) The Ester Enolate Claisen Rearrangement. I. Sterochemical Control Through Stereoselective Enolate Formation. II. Construction of the Prostanoid Skeleton. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/FX8A-9T58. https://resolver.caltech.edu/CaltechTHESIS:12042017-161832975 <https://resolver.caltech.edu/CaltechTHESIS:12042017-161832975>

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https://thesis.library.caltech.edu/10582/1/Willard_AK_1976.pdf
Willard, Alvin Keith (1976) The Ester Enolate Claisen Rearrangement. I. Sterochemical Control Through Stereoselective Enolate Formation. II. Construction of the Prostanoid Skeleton. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/FX8A-9T58. https://resolver.caltech.edu/CaltechTHESIS:12042017-161832975 <https://resolver.caltech.edu/CaltechTHESIS:12042017-161832975>

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