Catalytic Enantioselective Allylation of Imines and Trifluoroketones Using New and Underutilized Organoboron Reagents
Thesis advisor: Amir H. Hoveyda === A general method for the catalytic enantioselective addition of silylallenes to phosphinoyl aldimines has been developed. Reactions are promoted in the presence of 5.0 mol% of an N–heterocyclic carbene–copper complex and a silyl-protected propargyl boron reagent....
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| Format: | Others |
| Language: | English |
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Boston College
2017
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| Online Access: | http://hdl.handle.net/2345/bc-ir:107669 |