Synthesis of Z-(Pinacolato)allylboron and Z-(Pinacolato)alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis

Synthesis of Z-(Pinacolato)allylboron and Z-(Pinacolato)alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis

The first examples of catalytic cross-metathesis (CM) reactions that furnish Z-(pinacolato)allylboron and Z-(pinacolato)alkenylboron compounds are disclosed. Products are generated with high Z selectivity by the use of a W-based monoaryloxide pyrrolide (MAP) complex (up to 91% yield and >98:2 Z:E...

Full description

Bibliographic Details
Main Authors: Kiesewetter, Elizabeth T. (Author), O'Brien, Robert V. (Author), Yu, Elsie C. (Author), Meek, Simon J. (Author), Hoveyda, Amir H. (Author), Schrock, Richard Royce (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2015-02-25T19:21:07Z.
Subjects:
Article
Online Access:Get fulltext

Internet

Get fulltext

Similar Items