Charge transfer kinetics at the solid-solid interface in porous electrodes

Interfacial charge transfer is widely assumed to obey the Butler-Volmer kinetics. For certain liquid-solid interfaces, the Marcus-Hush-Chidsey theory is more accurate and predictive, but it has not been applied to porous electrodes. Here we report a simple method to extract the charge transfer rates...

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Bibliographic Details
Main Authors: Bai, Peng (Contributor), Bazant, Martin Z. (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemical Engineering (Contributor), Massachusetts Institute of Technology. Department of Mathematics (Contributor)
Format: Article
Language:English
Published: Nature Publishing Group, 2014-10-29T18:49:04Z.
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