Simplifying Nickel(0) Catalysis: An Air-stable, COD-free Nickel Precatalyst for the Internally-selective Benzylation of Terminal Alkenes
The synthesis and characterization of the air-stable nickel(II) complex trans-(PCy[subscript 2]Ph)[subscript 2]Ni(o-tolyl)Cl is described in conjunction with an investigation of its use for the Mizoroki-Heck-type, room temperature, internally selective coupling of substituted benzyl chlorides with t...
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2014-01-27T19:55:13Z.
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Subjects: | |
Online Access: | Get fulltext |