Directed Heterodimerization: Stereocontrolled Assembly via Solvent-Caged Unsymmetrical Diazene Fragmentation
A general strategy for the directed and stereocontrolled assembly of carbon-carbon linked heterodimeric hexahydropyrroloindoles is described. The stepwise union of complex amines in the form of mixed diazenes followed by photoexpulsion of dinitrogen in a solvent cage provides completely guided assem...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2013-11-18T20:18:53Z.
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Subjects: | |
Online Access: | Get fulltext |