Equilibration of Tyrosyl Radicals (Y[• over 356], Y[• over 731], Y[• over 730]) in the Radical Propagation Pathway of the Escherichia coli Class Ia Ribonucleotide Reductase
Escherichia coli ribonucleotide reductase is an α2β2 complex that catalyzes the conversion of nucleotides to deoxynucleotides using a diferric tyrosyl radical (Y[• over 122]) cofactor in β2 to initiate catalysis in α2. Each turnover requires reversible long-range proton-coupled electron transfer (PC...
Main Authors: | , , , , |
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Other Authors: | , , |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2013-11-12T14:28:07Z.
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Subjects: | |
Online Access: | Get fulltext |