Suppression of Phase Separation in LiFePO 4 Nanoparticles During Battery Discharge
Using a novel electrochemical phase-field model, we question the common belief that LiXFePO₄ nanoparticles always separate into Li-rich and Li-poor phases during battery discharge. For small currents, spinodal decomposition or nucleation leads to moving phase boundaries. Above a critical current den...
| Main Authors: | , |
|---|---|
| Other Authors: | , , |
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society,
2013-03-22T18:43:29Z.
|
| Subjects: | |
| Online Access: | Get fulltext |