Fundamental Studies of Molybdenum and Tungsten Methylidene and Metallacyclobutane Complexes

Fundamental Studies of Molybdenum and Tungsten Methylidene and Metallacyclobutane Complexes

Addition of ethylene to Mo(NAr)(CHCMe2Ph)(OHIPT)(Pyr) (NAr = N-2,6-i-Pr2C6H3, OHIPT = O-2,6-(2,4,6-i-Pr3C6H2)2C6H3, Pyr = NC4H4) led to the trigonal-bipyramidal metallacyclobutane complex Mo(NAr)(C3H6)(OHIPT)(Pyr), in which the imido and aryloxide ligands occupy axial positions. Mo(NAr)(C3H6)(OHIPT)...

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Main Authors: Schrock, Richard Royce (Contributor), Jiang, Annie J. (Contributor), Marinescu, Smaranda C. (Contributor), Simpson, Jeffrey H. (Contributor), Muller, Peter (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society, 2012-03-08T17:10:50Z.
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