Complexes of Platinum Group Metals with a Conformationally Locked Scorpionate in a Metal-Organic Framework: An Unusually Close Apical Interaction of Palladium(II)

We report synthetic strategies for installing platinum group metals (PGMs: Pd, Rh, Ir, and Pt) on a scorpionate-derived linker (TpmC*) within a metal-organic framework (MOF), both by room-temperature postsynthetic metalation and by direct solvothermal synthesis, with a wide range of metal loadings r...

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Bibliographic Details
Main Authors: Payne, Michael T (Author), Neumann, Constanze N (Author), Stavitski, Eli (Author), Dincǎ, Mircea (Author)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2022-07-22T11:57:49Z.
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