Gas Phase Ethylene Polymerization by Single-Site Cr Centers in a MetalOrganic Framework

Gas Phase Ethylene Polymerization by Single-Site Cr Centers in a MetalOrganic Framework

We report a systematic study on the gas-phase polymerization of ethylene by a metal-organic framework (MOF) catalyst. Cr3+-exchanged MFU-4l (Cr(III)-MFU-4l, MFU-4l = Zn5Cl4(BTDD)3, H2BTDD = bis(1H-1,2,3,-triazolo[4,5-b],[4',5'-i])dibenzo[1,4]dioxin)) serves as an exemplary system to demons...

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Main Authors: Park, Hoyoung Daniel (Author), Comito, Robert J. (Author), Wu, Zhenwei (Author), Zhang, Guanghui (Author), Ricke, Nathan Darrell (Author), Sun, Chenyue (Author), Van Voorhis, Troy (Author), Miller, Jeffrey T. (Author), Roman-Leshkov, Yuriy (Author), Dinca, Mircea (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Massachusetts Institute of Technology. Department of Chemical Engineering (Contributor)
Format: Article
Language:English
Published: 2020-06-03T18:50:44Z.
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