Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct
Allene (C₃H₄) gas is produced and separated on million-metric-ton scale per year during petroleum refining but is rarely employed in organic synthesis. Meanwhile, the addition of an allyl group (C₃H₅) to ketones is among the most common and prototypical reactions in synthetic chemistry. Herein, we r...
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2020-03-25T18:20:47Z.
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Online Access: | Get fulltext |