When Is Ligand pK[subscript a] a Good Descriptor for Catalyst Energetics? In Search of Optimal CO₂ Hydration Catalysts
We present a detailed study of nearly 70 Zn molecular catalysts for CO₂ hydration from four diverse ligand classes ranging from well-studied carbonic anhydrase mimics (e.g., cyclen) to new structures we obtain by leveraging diverse hits from large organic libraries. Using microkinetic analysis and e...
| Main Authors: | , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS),
2020-02-20T18:14:08Z.
|
| Subjects: | |
| Online Access: | Get fulltext |