Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity

Sulfur monoxide (SO) is a highly reactive molecule and thus, eludes bulk isolation. We report here on synthesis and reactivity of a molecular precursor for SO generation, namely 7-sulfin-ylamino-7-azadibenzonorbornadiene (1). This compound has been shown to fragment readily driven by dinitrogen expu...

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Bibliographic Details
Main Authors: Martin-Drumel (Author), McCarthy, Michael C. (Author), Patterson, David (Author), Joost, Maximilian G (Contributor), Nava, Matthew Jordan (Contributor), Transue, Wesley (Contributor), Cummins, Christopher C (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: National Academy of Sciences (U.S.), 2019-02-27T17:01:51Z.
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