Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds
Dibenzo-7-phosphanorbornadiene compounds, RPA (A = C₁₄H₁₀ or anthracene), are investigated as phosphinidene sources upon thermally induced (70-90 °C) anthracene elimination. Analysis of substituent effects reveals that π-donating dialkylamide groups are paramount to successful phosphinidene transfer...
Main Authors: | , , , , , |
---|---|
Other Authors: | , |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2018-07-30T18:51:55Z.
|
Subjects: | |
Online Access: | Get fulltext |