Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds

Dibenzo-7-phosphanorbornadiene compounds, RPA (A = C₁₄H₁₀ or anthracene), are investigated as phosphinidene sources upon thermally induced (70-90 °C) anthracene elimination. Analysis of substituent effects reveals that π-donating dialkylamide groups are paramount to successful phosphinidene transfer...

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Bibliographic Details
Main Authors: García-Iriepa, Cristina (Author), Temprado, Manuel (Author), Transue, Wesley (Contributor), Velian, Alexandra (Contributor), Nava, Matthew Jordan (Contributor), Cummins, Christopher C (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Cummins, Christopher C. (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2018-07-30T18:51:55Z.
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