Stable Open-Shell Phosphorane Based on a Redox-Active Amidodiphenoxide Scaffold
The synthesis and redox reactivity of pentacoordinate phosphorus compounds incorporating a redox-active ONO amidodiphenoxide scaffold [ONO = N,N-bis(3,5-di-tert-butyl-2-phenoxide)amide] are described. Dichloro- and diphenylphosphoranes, 2·Cl₂ and 2·Ph₂, respectively, are synthesized and crystallogra...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS),
2018-07-30T18:35:04Z.
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| Subjects: | |
| Online Access: | Get fulltext |