Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes
[Ar₂N₃]Mo(N)(O-t-Bu), which contains the conformationally rigid pyridine-based diamido ligand, [2,6-(ArNCH₂)₂NC₅H₃]²- (Ar = 2,6-diisopropylphenyl), can be prepared from H₂[Ar₂N₃], butyllithium, and (t-BuO)₃Mo(N). [Ar₂N₃]Mo(N)(O-t-Bu) serves as a catalyst or precursor for the catalytic reduction of m...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS),
2018-06-25T17:32:48Z.
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| Subjects: | |
| Online Access: | Get fulltext |