Reversing the Native Aerobic Oxidation Reactivity of Graphitic Carbon: Heterogeneous Metal-Free Alkene Hydrogenation
Commercially available carbon blacks serve as effective metal-free catalysts for the selective hydrogenation of carbon-carbon multiple bonds under aerobic conditions using hydrazine as the terminal reductant. The reaction, which proceeds through a putative diimide intermediate, displays high toleran...
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2018-05-01T14:22:58Z.
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Online Access: | Get fulltext |