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01639 am a22003013u 4500 |
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114955 |
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|a dc
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|a Wu, Zhenwei
|e author
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|a Massachusetts Institute of Technology. Department of Chemistry
|e contributor
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|a Dinca, Mircea
|e contributor
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|a Comito, Robert J
|e contributor
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|a Metzger, Eric Daniel
|e contributor
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|a Hendon, Christopher H
|e contributor
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|a Dinca, Mircea
|e contributor
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|a Zhang, Guanghui
|e author
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|a Miller, Jeffrey T.
|e author
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|a Comito, Robert J
|e author
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|a Metzger, Eric Daniel
|e author
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|a Hendon, Christopher H
|e author
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|a Dinca, Mircea
|e author
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|a Selective Dimerization of Propylene with Ni-MFU-4
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|b American Chemical Society (ACS),
|c 2018-04-25T17:53:20Z.
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| 856 |
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|z Get fulltext
|u http://hdl.handle.net/1721.1/114955
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|a We report the selective dimerization of propylene to branched hexenes using Ni-MFU-4l, a solid catalyst prepared by cation exchange. Analysis of the resulting product distribution demonstrates that the selectivity arises from 2,1-insertion and slow product reinsertion, mechanistic features reproduced by a molecular nickel tris-pyrazolylborate catalyst. Characterization of Ni-MFU-4l by X-ray absorption spectroscopy provides evidence for discrete, tris-pyrazolylborate-like coordination of nickel, underscoring the small-molecule analogy that can be made at metal-organic framework nodes.
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|a National Science Foundation (U.S.) (Award DMR-1452612)
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|a en_US
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7 |
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|a Article
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| 773 |
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|t Organometallics
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