Selective Dimerization of Propylene with Ni-MFU-4

Selective Dimerization of Propylene with Ni-MFU-4

We report the selective dimerization of propylene to branched hexenes using Ni-MFU-4l, a solid catalyst prepared by cation exchange. Analysis of the resulting product distribution demonstrates that the selectivity arises from 2,1-insertion and slow product reinsertion, mechanistic features reproduce...

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Bibliographic Details
Main Authors: Wu, Zhenwei (Author), Zhang, Guanghui (Author), Miller, Jeffrey T. (Author), Comito, Robert J (Contributor), Metzger, Eric Daniel (Contributor), Hendon, Christopher H (Contributor), Dinca, Mircea (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2018-04-25T17:53:20Z.
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