A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO{subscript 2]/ethylene coupling
A family of cis-macrocyclic diphosphines was prepared in just three steps from white phosphorus and commercial materials using a modular synthetic approach. Alkylation of bicyclic diphosphane 3,4,8,9-tetramethyl-1,6-diphosphabicyclo(4.4.0)deca-3,8-diene, or P[subscript 2](dmb)[subscript 2], produced...
Main Authors: | , , , , , |
---|---|
Other Authors: | |
Format: | Article |
Language: | English |
Published: |
Royal Society of Chemistry,
2018-04-13T18:22:48Z.
|
Subjects: | |
Online Access: | Get fulltext |