Improving dopant incorporation during femtosecond-laser doping of Si with a Se thin-film dopant precursor

• Main Authors: Sher, Meng-Ju (Author), Franta, Benjamin (Author), Lin, Yu-Ting (Author), Mazur, Eric (Author), Smith, Matthew J (Contributor), Gradecak, Silvija (Contributor)
• Other Authors: Massachusetts Institute of Technology. Department of Materials Science and Engineering (Contributor), Massachusetts Institute of Technology. Research Laboratory of Electronics (Contributor)
• Format: Article
• Language: English
• Published: Springer Berlin Heidelberg, 2017-03-23T22:44:18Z.
• Subjects: Article
• Online Access: Get fulltext

We study the dopant incorporation processes during thin-film fs-laser doping of Si and tailor the dopant distribution through optimization of the fs-laser irradiation conditions. Scanning electron microscopy, transmission electron microscopy, and profilometry are used to study the interrelated dopant incorporation and surface texturing mechanisms during fs-laser irradiation of Si coated with a Se thin-film dopant precursor. We show that the crystallization of Se-doped Si and micrometer-scale surface texturing are closely coupled and produce a doped surface that is not conducive to device fabrication. Next, we use this understanding of the dopant incorporation process to decouple dopant crystallization from surface texturing by tailoring the irradiation conditions. A low-fluence regime is identified in which a continuous surface layer of doped crystalline material forms in parallel with laser-induced periodic surface structures over many laser pulses. This investigation demonstrates the ability to tailor the dopant distribution through a systematic investigation of the relationship between fs-laser irradiation conditions, microstructure, and dopant distribution.
Chesonis Family Foundation
National Science Foundation (U.S.). Engineering Research Center for Quantum Energy and Sustainable Solar Technologies (EEC-1041895)
National Science Foundation (U.S.) (awards CBET 0754227 and CHE-DMRDMS 0934480)