Synthesis of Nanometer Sized Bis- and Tris-trityl Model Compounds with Different Extent of Spin–Spin Coupling

Synthesis of Nanometer Sized Bis- and Tris-trityl Model Compounds with Different Extent of Spin–Spin Coupling

Tris(2,3,5,6-tetrathiaaryl)methyl radicals, so-called trityl radicals, are emerging as spin labels for distance measurements in biological systems based on Electron Paramagnetic Resonance (EPR). Here, the synthesis and characterization of rigid model systems carrying either two or three trityl moiet...

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Bibliographic Details
Main Authors: J. Jacques Jassoy, Andreas Meyer, Sebastian Spicher, Christine Wuebben, Olav Schiemann
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Molecules
Subjects:
radicals
para-phenylene ethynylene
EPR
exchange coupling
pulsed dipolar spectroscopy
PELDOR
DEER
Online Access:http://www.mdpi.com/1420-3049/23/3/682

Internet

http://www.mdpi.com/1420-3049/23/3/682

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