Tetracarbonyl[bis(diphenylphosphanyl)tetramethyldisiloxane-κ2P,P′]chromium(0)
The title compound, [Cr(C28H32OP2Si2)(CO)4], was obtained by the ligand-exchange reaction of Cr(CO)6 with (Ph2PSiMe2)2O in refluxing toluene. The CrC4P2 coordination geometry is distorted octahedral, with a P—Cr—P bite angle of 99.22 (4)°.
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812000219 |