One-step Selective Synthesis of 13-epi-manoyl Oxide

The selective one-step synthesis of 13-epi-manoyl oxide is reported based on a low-temperature superacidic cyclization of sclareol. The reaction conditions have been finely tuned in order to achieve a 9:1 ratio between epimeric oxides in favor of the desired 13-epi-oxide.

Bibliographic Details
Main Authors:	Olga Morarescu, Marionela Traistari, Alic Barba, Gheorghe Duca, Nicon Ungur, Veaceslav Kulcițki
Format:	Article
Language:	English
Published:	Academy of Sciences of Moldova, Institute of Chemistry 2021-07-01
Series:	Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:	sclareol cyclization superacid ether labdane
Online Access:	http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2021.820-Kulcitki.pdf

id	doaj-fe9885feccab43f8b2b1936d67131a1f
record_format	Article
spelling	doaj-fe9885feccab43f8b2b1936d67131a1f2021-07-05T16:22:45ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882021-07-011619910410.19261/cjm.2021.820820One-step Selective Synthesis of 13-epi-manoyl OxideOlga Morarescu0Marionela Traistari1Alic Barba2Gheorghe Duca3Nicon Ungur4Veaceslav Kulcițki5 Institute of Chemistry, 3, Academiei str., Chisinau MD-2028, Republic of Moldova Moldova State University, 60, Mateevici str., Chisinau MD-2009, Republic of Moldova Institute of Chemistry, 3, Academiei str., Chisinau MD-2028, Republic of Moldova Institute of Chemistry, 3, Academiei str., Chisinau MD-2028, Republic of Moldova Institute of Chemistry, 3, Academiei str., Chisinau MD-2028, Republic of Moldova Institute of Chemistry, 3, Academiei str., Chisinau MD-2028, Republic of Moldova The selective one-step synthesis of 13-epi-manoyl oxide is reported based on a low-temperature superacidic cyclization of sclareol. The reaction conditions have been finely tuned in order to achieve a 9:1 ratio between epimeric oxides in favor of the desired 13-epi-oxide. http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2021.820-Kulcitki.pdf sclareolcyclizationsuperacidetherlabdane
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Olga Morarescu Marionela Traistari Alic Barba Gheorghe Duca Nicon Ungur Veaceslav Kulcițki
spellingShingle	Olga Morarescu Marionela Traistari Alic Barba Gheorghe Duca Nicon Ungur Veaceslav Kulcițki One-step Selective Synthesis of 13-epi-manoyl Oxide Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry sclareol cyclization superacid ether labdane
author_facet	Olga Morarescu Marionela Traistari Alic Barba Gheorghe Duca Nicon Ungur Veaceslav Kulcițki
author_sort	Olga Morarescu
title	One-step Selective Synthesis of 13-epi-manoyl Oxide
title_short	One-step Selective Synthesis of 13-epi-manoyl Oxide
title_full	One-step Selective Synthesis of 13-epi-manoyl Oxide
title_fullStr	One-step Selective Synthesis of 13-epi-manoyl Oxide
title_full_unstemmed	One-step Selective Synthesis of 13-epi-manoyl Oxide
title_sort	one-step selective synthesis of 13-epi-manoyl oxide
publisher	Academy of Sciences of Moldova, Institute of Chemistry
series	Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
issn	1857-1727 2345-1688
publishDate	2021-07-01
description	The selective one-step synthesis of 13-epi-manoyl oxide is reported based on a low-temperature superacidic cyclization of sclareol. The reaction conditions have been finely tuned in order to achieve a 9:1 ratio between epimeric oxides in favor of the desired 13-epi-oxide.
topic	sclareol cyclization superacid ether labdane
url	http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2021.820-Kulcitki.pdf
work_keys_str_mv	AT olgamorarescu onestepselectivesynthesisof13epimanoyloxide AT marionelatraistari onestepselectivesynthesisof13epimanoyloxide AT alicbarba onestepselectivesynthesisof13epimanoyloxide AT gheorgheduca onestepselectivesynthesisof13epimanoyloxide AT niconungur onestepselectivesynthesisof13epimanoyloxide AT veaceslavkulcitki onestepselectivesynthesisof13epimanoyloxide
_version_	1721318470002409472

One-step Selective Synthesis of 13-epi-manoyl Oxide

Similar Items