Correlation of the Rates of Solvolysis of Two Arenesulfonyl Chlorides and of trans-β-Styrenesulfonyl Chloride — Precursors in the Development of New Pharmaceuticals

Correlation of the Rates of Solvolysis of Two Arenesulfonyl Chlorides and of trans-β-Styrenesulfonyl Chloride — Precursors in the Development of New Pharmaceuticals

Additional specific rates of solvolysis have been determined, mainly in fluoroalcohol containing solvents, for benzenesulfonyl chloride (1) and p-nitrobenzenesulfonyl chloride (2). For trans-β-styrenesulfonyl chloride (3), a study has been carried out in 43 pure and binary solvents, covering a wi...

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Bibliographic Details
Main Authors: Zoon Ha Ryu, Sang Wok Lee, Lamia Yaakoubd, Dennis N. Kevill, Malcolm J. D’Souza, Samantha E. Feld
Format: Article
Language:English
Published: MDPI AG 2008-12-01
Series:International Journal of Molecular Sciences
Subjects:
Solvolysis
sulfonyl transfer
benzenesulfonyl chloride
paranitrobenzenesulfonyl chloride
trans-β-styrenesulfonyl chloride
Grunwald-Winstein equation
Linear Free Energy Relationships
kinetic solvent isotope effect
general base catalysis
Online Access:http://www.mdpi.com/1422-0067/9/12/2639/

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http://www.mdpi.com/1422-0067/9/12/2639/

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